【作者】：Abdurahman, A.; Shen, L.; Wang, J.; Niu, M.; Li, P.; Peng, Q.; Wang, J.; Lu, G.
【题目】：A highly efficient open-shell singlet luminescent diradical with strong magnetoluminescence properties
【关键词】：
【版面信息】：Light: Science & Applications 2023, 12, 272.
摘要:
Developing open-shell singlet (OS) diradicals with high luminescent properties and exceptional single-molecule magnetoluminescence (ML) performance is extremely challenging. Herein, we propose a concept to enhance luminescent efficiency by adjusting the donor conjugation of OS diradicals, thereby achieving a highly luminescent diradical, DR1, with outstanding stability and making it a viable option for use in the emitting layer of organic light-emitting diodes (OLEDs). More importantly, the 0.5wt%-DR1 doped film demonstrates significant single-molecule magnetoluminescence (ML) properties. A giant ML value of 210% is achieved at a magnetic field of 7T, showing the great potential of DR1 in magneto-optoelectronic devices.
原文链接：https://www.nature.com/articles/s41377-023-01314-z
